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N2O Lewis Structure| Nitrous oxide-Laughing Gas

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In the N2O Lewis structure, nitrogen (N) and oxygen (O) atoms are covalently bonded. The number of valence electrons in N and O is five and six, respectively. The total number of valence electrons in N2O is 16. N2O or nitrous oxide is commonly known as a laughing gas. Also, several other names by which this compound is known, such as sweet air, protoxide of Nitrogen, etc.

N2O lewis structure would comprise of two atoms of Nitrogen(N) and one oxygen atom. there is a triple bond with two nitrogens.
Name of molecule Nitrous oxide (N2O)
Bond Angles180 degrees
Molecular Geometry of N2O Linear
No of Valence Electrons in the molecule16
The dipole moment of N2O 0.160880 D [Reference]

N2O Lewis Structure (Step by Step Construction)

In the N2O Lewis structure, the overall ratio of Nitrogen to Oxygen atom is 2:1. The following are the steps to construct the Lewis Structure.

Step-1: Count the valence electrons of atoms.

For the N2O Lewis structure, we need to figure out the number of valence electrons in individual atoms as shown in the table.

AtomElectronic ConfigurationValence Electrons (VEs)
8O1S2 2S2 2P46
7N1S2 2S2 2P3.5

Valence electrons (VEs) in Nitrous Oxide = VEs in Oxygen atom + VEs in Nitrogen atoms
= 1(6)+2(5)
Valence electrons = 16 electrons.

in n2o lewis structure n is less electronegative than oxygen

Step-2: Determine the central atom

As per rule, N is placed in the middle because it’s less electronegative than Oxygen.
If we check the proper arrangement of N and Oxygen in the periodic table, we will find that the electronegativity of N is 3.0 and the electronegativity of O is 3.5.

dot structure of n20 shows that it has 16 valence electrons

Step-3: Place electron pairs between the atoms

We need to distribute the 16 remaining valence electrons. First, we will draw a skeletal structure with single bonds only.
Out of 16 electrons, 4 will be used in pairs between atoms. Now we have 12 valence electrons to distribute.
Nitrogen with 5 valence electrons needs 3 more electrons to fill the octet whereas Oxygen with 6 valence electrons needs 2 more electrons to complete the octet.

Three lewis structures of nitrous oxide-laughing gas. dots represent electrons and a single line represents a covalent bond

Step 4: Complete Octet


Give multiple bonds if required for fulfilling the octet of the atoms. At last, make sure all the atoms are having their lowest possible formal charge. The figure at the right shows three possible Lewis structures.

What is Nitrous Oxide

Nitrous oxide (N2O), is also known as laughing gas. It is important for a variety of medical applications because of its anesthetic use. It is insoluble in water and works as a powerful oxidizer at higher temperatures. It’s a colorless gas with a slightly sweet odor. It can cause a narcotic effect at higher concentrations. 

Laughing Gas

Nitrous oxide is a colorless, non-flammable gas. It’s also frequently referred to as “laughing gas” or “happy gas.” Hence, if a mixture of nitrogen oxide with a little oxygen is inhaled for a sufficiently long time, it produces hysterical laughter. Hence, nitrogen oxide is also known as “laughing gas”.
As a sedative, this gas is utilized in medical and dental operations. It assists in reducing anxiety and allows the patient to rest before the surgery.
You may open this link to laugh without laughing gas.

Molar Mass of Nitrous oxide

The molar mass of Oxygen =16.00 g/mol.
Nitrogen molar mass = 14.01 x 2 = 28.02 g/mol.
The molar mass of Nitrous oxide = 44.013 g/mol

N2O Lewis Structure – Key Points

nitrous oxide dot structure important points
  • The simplest formula for Nitrous oxide is N2O
  •  It is a famous inhaled anesthetic as it works as a quick pain reliever.
  • Molar mass of N2O is 44.013 g/mol
  • Nitrous oxide, from being used as an oxidizer in a rocket motor to its usage in internal combustion engines, has immense use in different fields. It is also used in aerosol propellants.
  • As per the N2O Lewis structure, the molecular geometry of N2O is linear.
  • It is used in the manufacturing of semiconductors
  • Number of electrons in the valence shell of nitrogen atom = 5
  • Number of electrons in the valence shell of oxygen atom = 6
  • The charge of the central nitrogen atom is +1 in the N2O molecule

N2O Formal Charge

Formal charge on n2o shows nitrogen charge is zero, central nitrogen charge is +1 and oxygen charge is -1

Formal charge = valence electrons – unbonded electrons – 0.5 bonded electrons
Valence electrons in Nitrogen = 5 electrons
Unbonded electrons in Nitrogen = 2 electrons
Half of the bonded electrons in Nitrogen =6/2 =3 electrons
Formal charge on Nitrogen = 5 – 2 – 3 = 0

Valence electrons in central Nitrogen = 5 electrons
Unbonded electrons in central Nitrogen = 0 electrons
Half of the bonded electrons in central Nitrogen =8/2 =4 electrons
Formal charge on central Nitrogen =5 – 0 – 4 =1 electron

Valence electrons in Oxygen = 6 electrons
Unbonded electrons in oxygen = 6 electrons
Half of the bonded electrons in oxygen are =2/2 =2 electrons.
Formal charge on oxygen = 6-6-1 = -1 electrons.

N2 Lewis Structure

N2 Lewis structure would comprise two atoms of nitrogen (N) atoms. There is a triple bond between both nitrogen atoms.
Each N is surrounded by two dots, which are called lone pairs of electrons.
These lone pairs (unbonded electrons) represent another 6 electrons in the N2 triple bond.
Therefore, in the N2 Lewis structure, each nitrogen atom is surrounded by 8 total valence electrons, giving it an octet and making it stable.
The molecular structure shows that the N2 molecule is perfectly symmetric.
Therefore, we can conclude that N2 is a nonpolar substance.

n2 lewis structure comprises two nitrogen atoms each contains a lone pair of electrons. There is a triple bond between both atoms.

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Frequently Asked Questions (FAQs)

Nitrous oxide is a neutral oxide. It does not form salt when reacted with acids or bases.

If a mixture of Nitrous Oxide with little Oxygen is inhaled for a sufficiently long time, it produces hysterical laughter.

Lewis structure of N2O helps us to find out about the structure of the compound, its types, the number of bonds, physical properties, and how the compound interacts with other compounds.

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Author
Umair Javed
Umair has been working at Whatsinsight since 2020 as a content writer.
He has a Masters degree in Materials Science.

Umair Javaid, PhD Student
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